Selenium acid and telluric acid
The highest oxidation states of selenium and tellurium corresponding to
selenic and telluric acids are obtained by the action of strong oxidants
(chloric, chromic) on selenic or telluric acids. They are separated in a
free state and are colorless crystalline substances that dissolve easily
in water. Selenic acid has two known crystalline hydrates: H2SeO4 * H2O
and H2SeO4 * 4H2O.
Pure selenic acid can be obtained by applying sulfuric acid to barium
selenate:
BaSeO 4 + H 2 SO 4 = BaSO 4 + H 2 SeO 4.
Concentrated selenic acid is a strong oxidant, which is better than
concentrated sulphuric acid (which is how H2SeO4 dissolves not only
silver but also gold).
Evaporation tellurium acid solution will generate crystalline hydrate Н
teo4 2 * 2 2 О Н. The hydrogen atoms that make up the crystalline
hydrate are characterized by their ability to be partially or completely
replaced by metals. For example, salt is known as Ag6TeO6, which
corresponds to the hexalkali, or so-called orthotelluric acid H6TeO6.
Telluric acid, unlike selenic acid, is very weak.
Sulfur dioxide reduces telluric acid to the element tellurium. At the
same time, selenic acid was reduced to selenite only by the reductant.
It can be used to separate tellurium from selenium.
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